Determination of Nitrite and Nitrate Level in Wastewater Discharge from Smoked Fish Industry
DOI:
https://doi.org/10.31938/jsn.v12i1.323Abstract
This research aimed to determine nitrite and nitrate contamination in wastewater discharge from the smoked fish industry around the fishpond area in Penatarsewu village, Sidoarjo East Java. Samples were taken from ten locations along The Alo River from September to November 2020. Nitrate and nitrite levels were determined by the Standard Method for Examination of Water and Wastewater 4500-NO2-B dan 4500-NO3-B. Nitrite formed a reddishpurple azo dye produced by coupling diazotized sulfanilamide with N-(1-naphthyl)-ethylene-diamine dihydrochloride after a visible spectrophotometer measured the complexes nitrite at wavelength 543 nm. Meanwhile, the Nitrate level was determined by ultraviolet spectrophotometer at a wavelength of 220 nm. The standard nitrite calibration curve was shown by the line equation y= 3,30361x-0,0028 and a determination coefficient of 0.9999. Whereas the standard nitrate was showed by the line equation y=0,2507x + 0,0067 and a determination coefficient 0,9996. The level of nitrate and nitrite in the sample ranged from 0.05-0.93mg / L 1,2-1,6 mg / L. According to a quality standard threshold value for nitrite and nitrate-based on the Government Regulation of the Republic of Indonesia (PPRI) No.82 2001 is 0,06mg/L and 10 mg/L, therefore it can be concluded that some samples are above the threshold value for nitrite level.
Keywords: Alo River,  nitate,  nitrite,  smoked fish,  spectrophotometer
Penentuan Kadar Nitrit dan Nitrat Pembuangan Limbah Cair Industri Ikan Asap
ABSTRAK
Penelitian bertujuan untuk menentukan tingkat kontaminasi nitrat dan nitrit pada limbah industri ikan asap di sekitar kawasan tambak ikan asap di Desa Penatarsewu, Sidoardjo, Jawa Timur. Sampel diambil dari 10 titik di areal sekitar tambak sepanjang badan Sungai Alo pada bulan September sampai November 2020. Penentuan kadar nitrat dan nitrit mengacu pada Standard Methods for the Examination Water and Wastewater 4500-NO2-B dan 4500-NO3-B. Nitrit membentuk kompleks ungu kemerahan yang dihasilkan dari kopling sulfanilamida dengan N-(1-naptil)-etilena-diamina dihidroklorida kemudian kadarnya ditentukan dengan spektrofotometer sinar tampak pada panjang gelombang 543 nm. Kadar nitrat ditentukan menggunakan spektrofotometer ultraviolet pada panjang gelombang 220 nm. Hasil pengukuran standar nitrit menghasilkan persamaan garis y=3,30361x-0,0028 dengan koefesien determinasi 0,999 dan standar nitrat menghasilkan persamaan garis y=0,2507x+0,0067 dengan koefesien determinasi 0,9996. Kadar nitrit dan nitrat secara berturut-turut berkisar antara 0,05-0,93 mg/L dan 1,2-1,6 mg/L. Berdasarkan nilai ambang batas baku mutu nitrit dan nitrat berdasarkan Peraturan Pemerintah Republik Indonesia (PPRI) No.82 tahun 2001 adalah 0,06 mg/L dan 10 mg/L, maka dapat disimpulkan bahwa beberapa sampel mengandung kadar nitrit di atas ambang batas.
Kata kunci : ikan asap, nitrat, nitrit, Sungai Alo, spektrofotometer
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References
American Public Health Association. (2017). Standard Methods. In R. Baird, A. D. Eaton., & E. W. Rice (Eds.), Standard Methods for the Examination of Water and Wastewater (23rd ed.). American Public Health Association. https://doi.org/10.1016/B978-0-12-382165-2.00237-3
Huang, J., Yang, P., Li, C., Guo, Y., Lai, B., Wang, Y., Feng, L., & Zhang, Y. (2015). Effect of Nitrite and Nitrate Concentrations on the Performance of AFB-MFC Enriched with High-Strength Synthetic Wastewater. Biotechnology Research International, 2015, 1–6. https://doi.org/10.1155/2015/798397
Kusumanti, I., Yulianti, W., & Jannah, N. (2021). Physiochemical property of wastewater discharged from smoked fish industry around fishponds area in Penatarsewu Village, Sidoardjo, East Java. IOP Conference Series: Earth and Environmental Science, 744(1), 012037. https://doi.org/10.1088/1755-1315/744/1/012037
Manahan SE, S. E. (2001). Manahan, Stanley E. “Frontmatter.†Energy.
PP RI. (2001). Peraturan Pemerintah Republik Indonesia Nomor 82 Tahun 2001 tentang Pengelolaan Kualitas Air dan Pengendalian Pencemaran Air. Peraturan Pemerintah Republik Indonesia, 1–41.
Riyanto, P. D. (2014). Validasi & Verifikasi Metode Uji Sesuai dengan ISO/IEC 17025 Laboratorium Pengujian dan Kalibrasi. DEEPUBLISH. https://play.google.com/books/reader?id=c0mlCgAAQBAJ&pg=GBS.PA17
Saputra, A. dony, Haerudin, & Widyorini, N. (2016). http://ejournal-s1.undip.ac.id/index.php/maquares. 5, 80–90.
Setiadi, T., Ismail, G. A., & Watari, T. (2019). Pedoman Pengolahan Air Limbah Industri Pengolahan Ikan di Indonesia Pedoman Pengolahan Air Limbah Industri Pengolahan Ikan di Indonesia Bulan Maret , 2019 Kerjasama teknis co-benefits approach KLHK Indonesia dan KLH Jepang. August 2020.
Sulistijowati, rieny S., Suhara, otong D., Nurhajati, J., Afrianto, E., & Udin, Z. (2011). Mekanisme Pengasapan Ikan. 65–92. http://repository.ung.ac.id/karyailmiah/show/240/mekanisme-pengasapan-ikan.html
Taziki, M., Ahmadzadeh, H., & A. Murry, M. (2016). Growth of Chlorella vulgaris in High Concentrations of Nitrate and Nitrite for Wastewater Treatment. Current Biotechnology, 4(4), 441–447. https://doi.org/10.2174/2211550104666150930204835
Yogafanny, E. (2015). Pengaruh Aktifitas Warga di Sempadan Sungai terhadap Kualitas Air Sungai Winongo. Jurnal Sains &Teknologi Lingkungan, 7(1), 29–40. https://doi.org/10.20885/jstl.vol7.iss1.art3
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