Isotherm Adsorption of Ion Phosphate from Vinasse Waste Using Quaternary Ammonium Polymer as Adsorbent in Term Effect of Temperature
DOI:
https://doi.org/10.31938/jsn.v14i2.720Keywords:
Vinasse, Phosphate, Adsorption, Polymer, Isotherm LangmuirAbstract
Vinasse liquid waste is a waste product resulting from the ethanol distillation process. Phosphate in high concentrations can harm the environment, such as by polluting water sources and underground surfaces. In this research, adsorption of phosphate ions was carried out in vinasse waste to remove these pollutants using quaternary ammonium polymers. The study examined the effect of vinasse waste sample temperature on the adsorption of phosphate ions. The first step in this work was to create a quaternary ammonium polymer utilising a one-pot technique using 2-[methacryloyloxy)ethyl trimethylammonium chloride solution, also referred to as META. Subsequently, the adsorption process was performed using temperature variations of 25, 30, 40, 50, and 60 . Phosphate ion adsorbance was measured with UV-Vis spectrometers at a wavelength of 880 nm. The quaternary ammonium polymer succeeded in adsorbing the phosphate ion content of the vinasse waste at an optimal temperature of 40 , with an adsorption capacity of 3.78 mg/L and a removal efficiency of 75.70%. The adsorption isotherm model for phosphate ions onto quaternary ammonium polymer was studied using the Freundlich and Langmuir equations. The obtained data indicated that the Langmuir isotherm model, with an value of 0.9921, is well-suited for describing the adsorption behaviour in this research.
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Aini, N., Mufandi, I., Jamilatun, S., & Rahayu, A. (2023). Exploring Cacao Husk Waste – Surface Modification, Characterization, and its Potential for Removing Phosphate and Nitrate Ions. Journal of Ecological Engineering, 24(12), 282–292. https://doi.org/10.12911/22998993/174003
Albatrni, H., Qiblawey, H., Almomani, F., Adham, S., & Khraisheh, M. (2019). Polymeric adsorbents for oil removal from water. Chemosphere, 233, 809–817. https://doi.org/10.1016/j.chemosphere.2019.05.263
Álvarez, O. E. R., Nicolás Vázquez, M. I., Oñate-Garzón, J., & Arango, C. A. (2021). Validation by molecular dynamics of the major components of sugarcane vinasse, on a surface of calcium carbonate (Calcite). Molecules,26(8),1–11. https://doi.org/10.3390/molecules26082353
Christofoletti, C. A., Escher, J. P., Correia, J. E., Marinho, J. F. U., & Fontanetti, C. S. (2013). Sugarcane vinasse: Environmental implications of its use. Waste Management, 33(12),2752–2761. https://doi.org/10.1016/j.wasman.2013.09.005
Colin, V. L., Juárez Cortes, Á. A., Aparicio, J. D., & Amoroso, M. J. (2016). Potential application of a bioemulsifier-producing actinobacterium for treatment of vinasse. Chemosphere, 144, 842–847. https://doi.org/10.1016/j.chemosphere.2015.09.064
Fagier, M. A., Ali, E. A., Tay, K. S., & Abas, M. R. B. (2016). Mineralization of organic matter from vinasse using physicochemical treatment coupled with Fe2+-activated persulfate and peroxymonosulfate oxidation. International Journal of Environmental Science and Technology, 13(4),1189–1194. https://doi.org/10.1007/s13762-016-0963-x
Fito, J., Tefera, N., & Van Hulle, S. W. H. (2019). Sugarcane biorefineries wastewater: bioremediation technologies for environmental sustainability. Chemical and Biological Technologies in Agriculture, 6(1), 1–13. https://doi.org/10.1186/s40538-019-0144-5
Hoarau, J., Caro, Y., Grondin, I., & Petit, T. (2018). Sugarcane vinasse processing: Toward a status shift from waste to valuable resource. A review. Journal of Water Process Engineering, 24(January), 11–25. https://doi.org/10.1016/j.jwpe.2018.05.003
Loganathan, P., Vigneswaran, S., Kandasamy, J., & Bolan, N. S. (2014). Removal and recovery of phosphate from water using sorption. Critical Reviews in Environmental Science and Technology, 44(8), 847–907. https://doi.org/10.1080/10643389.2012.741311
Lorenzo-Santiago, M. A., Rodríguez-Campos, J., Rendón-Villalobos, R., García-Hernández, E., Vallejo-Cardona, A. A., & Contreras-Ramos, S. M. (2023). Thermal Treatment to Obtain 5-Hydroxymethyl Furfural (5-HMF), Furfural and Phenolic Compounds from Vinasse Waste from Agave. Molecules, 28(3). https://doi.org/10.3390/molecules28031063
Meila Anggriani, U., Hasan, A., & Purnamasari, I. (2021). Kinetika Adsorpsi Karbon Aktif Dalam Penurunan Konsentrasi Logam Tembaga (Cu) dan Timbal (Pb). Universitas Sriwijaya, 12(02), 29–37. https://jurnal.polsri.ac.id/index.php/kimia/index
Mekonnen, D. T., Alemayehu, E., & Lennartz, B. (2020). Removal of phosphate ions from aqueous solutions by adsorption onto leftover coal. Water (Switzerland), 12(5), 1–15. https://doi.org/10.3390/W12051381
Moraes, B. S., Zaiat, M., & Bonomi, A. (2015). Anaerobic digestion of vinasse from sugarcane ethanol production in Brazil: Challenges and perspectives. Renewable and Sustainable Energy Reviews, 44, 888–903. https://doi.org/10.1016/j.rser.2015.01.023
Nguyen, T. A. H., Ngo, H. H., Guo, W. S., Nguyen, T. V., Zhang, J., Liang, S., Chen, S. S., & Nguyen, N. C. (2014). A comparative study on different metal loaded soybean milk by-product “okara” for biosorption of phosphorus from aqueous solution. Bioresource Technology, 169, 291–298. https://doi.org/10.1016/j.biortech.2014.06.075
Rabiatul, S., Islam, U., Alauddin, N., Sutarno, S., Mada, U. G., Suyanta, S., & Mada, U. G. (2020). Indonesian Journal of Chemical Research Adsorption-Desorption Studies of Phosphate on CTAB Modified Bentonite Indonesian Journal of Chemical Research. January. https://doi.org/10.30598/ijcr.2020.8-sra
Rahayu, A., Hakika, D. C., Alfi, N., Amrillah, Z., & Veranica, V. (2023). Synthesis and characterization of ammonium polymer for anion removal in aqueous solutions. 10, 537–543. https://doi.org/10.14314/polimery.2023.10.3
Rahayu, A., Jamilatun, S., Fajri, J. A., & Lim, L. W. (2021). Characterization of Organic Polymer Monolith Columns Containing Ammonium Quaternary As Initial Study For Capillary Chromatography. Elkawnie, 7(1), 119. https://doi.org/10.22373/ekw.v7i1.8764
Reis, C. E. R., Bento, H. B. S., Alves, T. M., Carvalho, A. K. F., & De Castro, H. F. (2019). Vinasse treatment within the sugarcane-ethanol industry using ozone combined with anaerobic and aerobic microbial processes. Environments - MDPI, 6(1). https://doi.org/10.3390/environments6010005
Schindler, D. W., Carpenter, S. R., Chapra, S. C., Hecky, R. E., & Orihel, D. M. (2016). Reducing phosphorus to curb lake eutrophication is a success. Environmental Science and Technology, 50(17), 8923–8929. https://doi.org/10.1021/acs.est.6b02204
Víctor-Ortega, M. D., Ochando-Pulido, J. M., & Martinez-Ferez, A. (2016). Phenols removal from industrial effluents through novel polymeric resins: Kinetics and equilibrium studies. Separation and Purification Technology,160. https://doi.org/10.1016/j.seppur.2016.01.023
Yadav, D., Kapur, M., Kumar, P., & Mondal, M. K. (2015). Adsorptive removal of phosphate from aqueous solution using rice husk and fruit juice residue. Process Safety and Environmental Protection, 94(C), 402–409. https://doi.org/10.1016/j.psep.2014.09.005
Zhang, Y., & Li, R. (2021). Effect of Reaction Temperature on Adsorption Efficiency using Computer Mathematical Statistics Visible Spectorphotometer. Journal of Physics: Conference Series, 2083(3), 0–6. https://doi.org/10.1088/1742-6596/2083/3/032072
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Copyright (c) 2024 Veranica, Aster Rahayu, Maryudi, Dhias Cahya Hakika, Lee Wah Lim, Lia Anggresani
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