Combination Technique of AOP-Fenton and Photocatalysisi Using TiO2/Zeolit Coal Fly Ash Nanocomposite for Laboratory Waste Water
DOI:
https://doi.org/10.31938/jsn.v15i2.781Keywords:
AOP-Fenton, Photocatalysis, Waste Water, TiO2/Zeolite, NanocompositeAbstract
The increase in student practical activities will raise the amount of liquid waste generated from practical and research activities in higher education laboratories. The liquid waste must be specially treated before being discharged into water bodies. An alternative for laboratory waste treatment is the AOP method, specifically the Fenton process and photocatalysis. This study aims to determine the final results of laboratory liquid waste treatment using the AOP Fenton process and photocatalysis with TiO2/Coal Zeolite nanocomposite, testing parameters such as COD, BOD, TSS, and TDS. The results of waste treatment using the AOP-Fenton technique showed an increase in efficiency in reducing the values of the four parameters: COD 92.8%; BOD 92.6%; TSS 62.30%; and TDS 37.6%. The treatment process continued with photocatalysis under optimum conditions of pH 4, catalyst dose of 0.8 grams, and radiation time of 180 minutes, showing an increase in efficiency for the four parameters: COD 97.05%; BOD 98.3%; TSS 86.1%; and TDS 81.6%. The final waste analysis results for the four parameters were compared with PERMEN LH No. 5 of 2014. It is concluded that the waste concentration meets the standard quality criteria for category 1 waste.
Downloads
References
Afzal, T., Isa, M. H., & Raza Ul Mustafa, M. (2018). Removal of organic pollutants from produced water using Fenton oxidation. E3S Web of Conferences, 34. https://doi.org/10.1051/e3sconf/20183402035
Andarini, N., Wardhani, S., & Khunur, M. (2013). Fotodegradasi Zat Warna Jingga Metil Menggunakan TiO2- Zeolit dengan Penambahan Anion Anorganik NO3-. Kimia Student Journal, 1(1), 98–04.
Fatimah, I., Wijayana, A., Dwiki Ramanda, G., Suratno, Sagadevan, S., Oh, W. C., & Doong, R. an. (2024). Highly active photocatalyst of nickel oxide nanoparticles green-synthesized using Tinosphora cordifolia-plant extract for photocatalytic oxidation of tetracycline. Environmental Nanotechnology, Monitoring and Management, 22. https://doi.org/10.1016/j.enmm.2024.100968
Ghosh, S., Zhang, G., Chen, Y., & Hu, J. (2025). The efficacies of degrading antibiotic resistance genes (ARGs) by applying UV light emitting diodes (UV-LEDs) based advanced oxidation processes (AOPs). Water Research, 276. https://doi.org/10.1016/j.watres.2025.123197
Prakoso, I., Yunda Maharani, K., Rizki Ariq, M., Nurul Indah, A., Nurulindah Utami, A., Iryani, A., Syahputri, Y., & Jati Kusumawardani, L. (2024). Photodegradation of Methyl Orange (MO) Using TiO 2 /Zeolite from Coal Fly Ash Waste Under Acidic Conditions and H 2 O 2 Addition. Helium: Journal of Science and Applied Chemistry, 04(01). https://journal.unpak.ac.id/index.php/he_jsac
Jamil, T. (2024). Role of advance oxidation processes (AOPs) in textile wastewater treatment: A critical review. In Desalination and Water Treatment (Vol. 318). Elsevier B.V. https://doi.org/10.1016/j.dwt.2024.100387
Kang, Y. W., & Hwang, K.-Y. (2000). Effects of Reaction Conditions on The Oxidation Efficiency In The Fenton Process. www.elsevier.com/locate/watres
Kim, M. G., Kang, J. M., Lee, J. E., Kim, K. S., Kim, K. H., Cho, M., & Lee, S. G. (2021). Effects of Calcination Temperature on the Phase Composition, Photocatalytic Degradation, and Virucidal Activities of TiO2Nanoparticles. ACS Omega, 6(16), 10668–10678. https://doi.org/10.1021/acsomega.1c00043
Koundle, P., Nirmalkar, N., Momotko, M., Makowiec, S., & Boczkaj, G. (2024). Tetracycline degradation for wastewater treatment based on ozone nanobubbles advanced oxidation processes (AOPs) – Focus on nanobubbles formation, degradation kinetics, mechanism and effects of water composition. Chemical Engineering Journal, 501. https://doi.org/10.1016/j.cej.2024.156236
Kusumawardani, L. J., & Iryani, A. (2021). Photocatalytic Degradation of Phenol Using TiO2-Fe Under H2O2 Presence by Visible and Sunlight Irradiation. Jurnal Kimia Valensi, 7(2), 94–99. https://doi.org/10.15408/jkv.v7i2.20766
Kusumawardani, L. J., Iryani, A., & Sinaga, E. L. (2023). Modification of Zeolite Made from Coal Fly Ash with TiO2: Effect of Aging Time on Physical and Optical Properties. Makara Journal of Science, 27(1). https://doi.org/10.7454/mss.v27i1.1483
Kusumawardani, L. J., Syahputri, Y., & Iryani, A. (2020). Photocatalytic Degradation of Paraquat Dichloride using TiO2-Fe Nano Powder under Visible and Sunlight Irradiation. Jurnal Kimia Valensi, 6(1), 54–60. https://doi.org/10.15408/jkv.v6i1.13625
Kusumawardani, L. J., Widyyanti, T., Iryani, A., Hasanah, U., & Nurlela, N. (2024). Optimization and Mechanism Elucidation of Catalytic Photodegradation Methylene Blue by TiO2/Zeolite Coal Fly Ash Nanocomposite Under H2O2 Presence. Jurnal Sains Natural, 14, 98–108. https://doi.org/10.31938/jsn.v
Lubis, I. S., Ramli, M., & Sheilatina. (2016). Photocatalytic Degradation of Indigo Carmine by TiO2/Activated Carbon Derived From Waste Coffee Grounds. Jurnal Natural, 16(1), 21–26.
Mahedy, L., Hammerton, G., Teyhan, A., Edwards, A. C., Kendler, K. S., Moore, S. C., Hickman, M., MacLeod, J., & Heron, J. (2017). Parental alcohol use and risk of behavioral and emotional problems in offspring. PLoS ONE, 12(6). https://doi.org/10.1371/journal.pone.0178862
Imanudin, N. (2022). Pengolahan Limbah Cair di Laboratorium Menggunakan Metode Advanced Oxidation Processes (AOP: H2O2-Fe2+ ).
Rajaram, P., Jeice, A. R., & Jayakumar, K. (2024). Influences of calcination temperature on titanium dioxide nanoparticles synthesized using Averrhoa carambola leaf extract: in vitro antimicrobial activity and UV-light catalyzed degradation of textile wastewater. Biomass Conversion and Biorefinery, 14(17), 20665–20678. https://doi.org/10.1007/s13399-023-04212-x
Sukmawardani, Y., & Amalia, V. (2019). Chemistry Laboratorium Liquid Waste Treatment Using Electrocoagulation Method. Jurnal Kartika Kimia, 2(2). https://doi.org/10.26874/jkk.v2i2.29
Sulistyanti, D., Antoniker, A., & Nasrokhah, N. (2018). Penerapan Metode Filtrasi dan Adsorpsi pada Pengolahan Limbah Laboratorium. EduChemia (Jurnal Kimia Dan Pendidikan), 3(2), 147. https://doi.org/10.30870/educhemia.v3i2.2430
Zhang, G., Song, A., Duan, Y., & Zheng, S. (2018). Enhanced photocatalytic activity of TiO2/zeolite composite for abatement of pollutants. Microporous and Mesoporous Materials, 255, 61–68. https://doi.org/10.1016/j.micromeso.2017.07.028
Zhang, M., & Li, X. (2024). Quantitative analysis of research literature on degradation of pollutants by Fenton and Fenton-like AOPs based on CiteSpace. In Desalination and Water Treatment, 320. Elsevier B.V. https://doi.org/10.1016/j.dwt.2024.100894
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2025 Linda Jati Kusumawardani, Yulian Syahputri, Agel Figo Alfarosi

This work is licensed under a Creative Commons Attribution-ShareAlike 4.0 International License.















