Detection of Pb(II) and Cr(III) Using Dy(III) Ion with Pyrazoline Derivatives Ligand

Yulian Syahputri; Sutanto; M. Daud Mahmudin; Mohammad Rommy Izha Ramadhan

doi:10.31938/jsn.v14i3.733

Detection of Pb(II) and Cr(III) Using Dy(III) Ion with Pyrazoline Derivatives Ligand

Authors

Yulian Syahputri Universitas Pakuan
Sutanto Universitas Pakuan
M. Daud Mahmudin
Mohammad Rommy Izha Ramadhan

DOI:

https://doi.org/10.31938/jsn.v14i3.733

Keywords:

dysprosium, complex compound, fluorescence, heavy metal, pyrazoline

Abstract

Exposure to heavy metal ions Pb²⁺ and Cr³⁺ in Indonesia is getting more attention, especially in various industries and transportation. The sensor complex compound Dy³⁺ with fluorescence-based pyrazoline-derived ligands (fluorosensor) has the potential to detect heavy metal ions Pb²⁺ and Cr²⁺. This research was initiated by synthesizing the pyrazoline derivative ligand and then reacting it with Dy³⁺ metal ion. The formed Dy³⁺ complex compounds was then characterized using spectroscopic methods. The results of scanning complex compounds using a UV-Vis spectrophotometer obtained two maximum wavelengths namely at 255 and 359 nm are indicating the presence of a transition type n→π* and π→π*. The results of fluorescence spectrophotometer analysis obtained maximum fluorescence intensity of Dy³⁺ complex compound was in the wavelength at 370 nm with fluorescence intensity of 4273 a.u. Fluorescence based sensor studies of the Dy complex when Pb²⁺ and Cr³⁺ metal ions were added showed changes in fluorescence intensity so that the fluorosensor type was obtained for the Dy³⁺ metal ion complex compound with Pb²⁺ and Cr³⁺, namely "turn-on-off" and "turn-off" respectively.

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